Search results for "GE-DOPED SIO2"

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Effect of oxygen deficiency on the radiation sensitivity of sol-gel Ge-doped amorphous SiO2

2008

We report experimental investigation by electron paramagnetic resonance (EPR) measurements of room temperature γ-ray irradiation effects in sol-gel Ge doped amorphous SiO2. We used materials with Ge content from 10 up to 104 part per million (ppm) mol obtained with different preparations. These latter gave rise to samples characterized by different extents of oxygen deficiency, estimated from the absorption band at ~5.15 eV of the Ge oxygen deficient centers (GeODC(II)). The irradiation at doses up to ~400 kGy induces the E'-Ge, Ge(1) and Ge(2) paramagnetic centers around g ~ 2 with concentrations depending on Ge and on GeODC(II) content. We found correlation between Ge(2) and GeODC(II) con…

Materials scienceDopingAnalytical chemistrychemistry.chemical_elementradiation sensitivityCondensed Matter PhysicsOxygenElectronic Optical and Magnetic Materialslaw.inventionAmorphous solidParamagnetismNuclear magnetic resonancechemistrylawAbsorption bandGe-doped SiO2IrradiationSiO2Electron paramagnetic resonanceDisordered structureamorphous and glassy solidsSol-gelThe European Physical Journal B
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H(II) centers in natural silica under repeated UV laser irradiations

2004

We investigated the kinetics of H(II) centers (=Ge'-H) in natural silica under repeated 266nm UV irradiations performed by a Nd:YAG pulsed laser. UV photons temporarily destroy these paramagnetic defects, their reduction being complete within 250 pulses. After re-irradiation, H(II) centers grow again, and the observed recovery kinetics depends on the irradiation dose; multiple 2000 pulses re-irradiations induce the same post-irradiation kinetics of H(II) centers after each exposure cycle. The analysis of these effects allows us to achieve a deeper understanding of the dynamics of the centers during and after laser irradiation.

Pulsed laserKineticsTWOFOLD COORDINATED SIFOS: Physical sciencesATOMSParamagnetismMaterials ChemistryUv laserIrradiationEXPOSUREQuartzCondensed Matter - Materials ScienceSNChemistryNatural compoundRadiochemistryMaterials Science (cond-mat.mtrl-sci)Disordered Systems and Neural Networks (cond-mat.dis-nn)DEFECTSCondensed Matter - Disordered Systems and Neural NetworksCondensed Matter PhysicsDIFFUSIONElectronic Optical and Magnetic MaterialsWavelengthGE-DOPED SIO2MOLECULAR-HYDROGENGLASSESCeramics and Composites
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